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45214-91-3

  • Product NameBoc-L-glutamic acid 5-methyl ester
  • Molecular FormulaC11H19NO6
  • Molecular Weight261.275
  • Purity99%
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Product Details

Quick Details

  • CasNo： 45214-91-3
  • Molecular Formula： C11H19NO6
  • Purity： 99%

Buy Quality Boc-L-glutamic acid 5-methyl ester 45214-91-3 In Bulk Supply

  • Molecular Formula:C11H19NO6
  • Molecular Weight:261.275
  • Melting Point:119-123 °C 
  • Boiling Point:428.35 °C at 760 mmHg 
  • PKA:3.82±0.10(Predicted) 
  • Flash Point:212.859 °C 
  • PSA：101.93000 
  • Density:1.183 g/cm3 
  • LogP:1.30840 

BOC-GLU(OME)-OH(Cas 45214-91-3) Usage

Uses

N-Boc-L-glutamic Acid 5-Methyl Ester is an intermediate used in the synthesis of Isodesmosine Chloride Hydrate (Synthetic) (I815051), which is a component of elastin and also it is extremely hygroscopic and must be stored over a desiccant such as silica gel.

Isomeric SMILES: CC(C)(C)OC(=O)N[C@@H](CCC(=O)OC)C(=O)O  
InChIKey: OHYMUFVCRVPMEY-ZETCQYMHSA-N  
InChI: InChI=1S/C11H19NO6/c1-11(2,3)18-10(16)12-7(9(14)15)5-6-8(13)17-4/h7H,5-6H2,1-4H3,(H,12,16)(H,14,15)/t7-/m0/s1  

45214-91-3 Relevant articles

Facile reduction of ethyl thiol esters to aldehydes: application to a total synthesis of (+)-neothramycin A methyl ether

T Fukuyama, SC Lin, L Li

J. Am. Chem. Soc. 1990, 112, 19, 7050–7051

… from racemic glutamic acid 5-methyl ester exhibited two … derived from L-glutamic acid 5methyl ester showed only a singlet at … iV-Boc-L-glutamic dithiol ester 67 was acylated with the acid …

NOVEL JAK1 SELECTIVE INHIBITORS AND USES THEREOF

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Page/Page column 47, (2018/04/21)

The new 1H-furo[3,2-b]imidazo[4,5-d]pyri...

Constrained Cyclic β,γ-Diamino Acids from Glutamic Acid: Synthesis of Both Diastereomers and Unexpected Kinetic Resolution

Wan, Yang,Auberger, Nicolas,Thétiot-Laurent, Sophie,Bouillère, Francelin,Zulauf, Ana?s,He, Jiefang,Courtiol-Legourd, Stéphanie,Guillot, Régis,Kouklovsky, Cyrille,Cote des Combes, Sylvain,Pacaud, Christophe,Devillers, Ingrid,Alezra, Valérie

, p. 329 - 340 (2018/01/27)

We describe here an efficient synthesis ...

45214-91-3 Process route

(S)-(-)-1-tert-butyl-5-methyl-<(2-tert-butoxycarbonyl)amino>pentanedioate
24277-38-1

(S)-(-)-1-tert-butyl-5-methyl-<(2-tert-butoxycarbonyl)amino>pentanedioate

Boc-Glu
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Boc-Glu

(2S)-2-[(tert-butoxy)carbonylamino]-4-(methoxycarbonyl)butanoic acid
45214-91-3

(2S)-2-[(tert-butoxy)carbonylamino]-4-(methoxycarbonyl)butanoic acid

N-tert-butoxycarbonyl glutamic acid tert-butyl ester
24277-39-2

N-tert-butoxycarbonyl glutamic acid tert-butyl ester

Conditions
Conditions Yield
With Candida antarctica lipase; phosphate buffer; In methanol; hexane; at 37 ℃; for 48h;
20%
31%
19%
D-glutamic acid-5-methyl ester; hydrochloride
27025-22-5

D-glutamic acid-5-methyl ester; hydrochloride

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41840-28-2

S-tert-butoxycarbonyl-4,6-dimethyl-2-mercaptopyrimidine

N-α-(tert-butoxycarbonyl)-D-glutamic acid γ-methyl ester
45214-91-3,76379-01-6,112159-16-7

N-α-(tert-butoxycarbonyl)-D-glutamic acid γ-methyl ester

Conditions
Conditions Yield
With hydrogenchloride; triethanolamine; triethylamine; In water; N,N-dimethyl-formamide;
 

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