Your Location：Home >Products >Biochemical Engineering >102089-74-7

102089-74-7

  • Product NameBoc-D-Phenylglycinol
  • Molecular FormulaC13H19NO3
  • Molecular Weight237.299
  • Purity99%
  • Appearancewhite to light yellow crystal powder
Inquiry

Product Details

Quick Details

  • CasNo： 102089-74-7
  • Molecular Formula： C13H19NO3
  • Appearance： white to light yellow crystal powder
  • Purity： 99%

Fast Delivery Pharma Grade Boc-D-Phenylglycinol 102089-74-7

  • Molecular Formula:C13H19NO3
  • Molecular Weight:237.299
  • Appearance/Colour:white to light yellow crystal powder 
  • Vapor Pressure:2.4E-05mmHg at 25°C 
  • Melting Point:137-139 °C(lit.) 
  • Refractive Index:1.547 
  • Boiling Point:382.4 °C at 760 mmHg 
  • PKA:11.55±0.46(Predicted) 
  • Flash Point:185 °C 
  • PSA：58.56000 
  • Density:1.102 g/cm3 
  • LogP:2.63560 

(R)-N-(tert-Butoxycarbonyl)-2-phenylglycinol(Cas 102089-74-7) Usage

Chemical Properties

white to light yellow crystal powde

Uses

Chiral building block
European Community (EC) Number 600-273-1
DSSTox Substance ID DTXSID00426847

Isomeric SMILES: CC(C)(C)OC(=O)N[C@@H](CO)C1=CC=CC=C1  
InChIKey: IBDIOGYTZBKRGI-NSHDSACASA-N  
InChI: InChI=1S/C13H19NO3/c1-13(2,3)17-12(16)14-11(9-15)10-7-5-4-6-8-10/h4-8,11,15H,9H2,1-3H3,(H,14,16)/t11-/m0/s1  

102089-74-7 Relevant articles

Protic ionic liquid [TMG][Ac] as an efficient, homogeneous and recyclable catalyst for Boc protection of amines

Akbari, Jafar,Heydari, Akbar,Ma'mani, Leila,Hassan Hosseini, Seyed

, p. 544 - 547 (2010)

An efficient and practical protocol for ...

Chiral oxazolidinones from N-Boc derivatives of β-amino alcohols. Effect of a N-methyl substituent on reactivity and stereoselectivity

Agami, Claude,Couty, Francois,Hamon, Louis,Venier, Olivier

, p. 4509 - 4512 (1993)

Treatment of N-tert-butoxycarbonyl deriv...

A new scaffold for amide ligation

Marinzi, Chiara,Bark, Steven J.,Offer, John,Dawson, Philip E.

, p. 2323 - 2328 (2001)

Highly chemoselective amide forming liga...

A mild and selective cleavage of p-methoxybenzyl Ethers by CBr4-MeOH

Yadav,Reddy, B. V. Subba

, p. 566 - 567 (2000)

p-Methoxybenzyl ethers were selectively ...

Platinum nanoparticles supported on zirconia mediated synthesis of N-acyl and N-(tert-butoxycarbonyl)amines from nitroarenes and azides

Kantam, M. Lakshmi,Reddy, R. Sudarshan,Srinivas,Chakravarti,Sreedhar,Figueras,Venkat Reddy, Ch.

, p. 96 - 101 (2012)

A convenient and useful protocol has bee...

ZnO nanorods as an efficient and heterogeneous catalyst for N-Boc protection of amines and amine derivatives

Nouria, Azita,Akbari, Jafar,Heydaric, Akbar,Nouri, Arezu

, p. 38 - 42 (2011)

An efficient ZnO nano catalyst, which wa...

Construction and activity evaluation of novel dual-target (SE/CYP51) anti-fungal agents containing amide naphthyl structure

An, Yunfei,Fan, Haiyan,Han, Jun,Liu, Wenxia,Liu, Yating,Sun, Bin,Sun, Zhuang

, (2021/11/16)

With the increase of fungal infection an...

Organoiodine-Catalyzed Enantioselective Intermolecular Oxyamination of Alkenes

Wata, Chisato,Hashimoto, Takuya

supporting information, p. 1745 - 1751 (2021/02/05)

Metal-free, catalytic enantioselective i...

102089-74-7 Process route

2-(tert-butoxycarbonylamino)-2-phenylacetic acid
2900-27-8,3601-66-9,14675-97-9,33125-05-2

2-(tert-butoxycarbonylamino)-2-phenylacetic acid

tert-butyl 2-hydroxy-1-phenylethylcarbamate
102089-74-7,117049-14-6,138457-46-2,67341-01-9

tert-butyl 2-hydroxy-1-phenylethylcarbamate

Conditions
Conditions Yield
2-(tert-butoxycarbonylamino)-2-phenylacetic acid; With borane-THF; In tetrahydrofuran; at 0 ℃;
With water; ammonium chloride; In tetrahydrofuran;
 
di-<i>tert</i>-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

Phenylglycinol
20989-17-7,56613-80-0,71006-16-1,7568-92-5,188586-38-1

Phenylglycinol

tert-butyl 2-hydroxy-1-phenylethylcarbamate
102089-74-7,117049-14-6,138457-46-2,67341-01-9

tert-butyl 2-hydroxy-1-phenylethylcarbamate

Conditions
Conditions Yield
With triethylamine; In dichloromethane; at 20 ℃; for 6h;
91.7%
With triethylamine; In dichloromethane; at 20 ℃;
90%
With aminosulfonic acid; at 30 ℃;
84%
With sodium hydroxide; In dichloromethane; Ambient temperature;
83%
With sodium hydroxide; In diethyl ether; water;
 
In dichloromethane; at 20 ℃; for 3h;
 
With triethylamine; In dichloromethane; for 12h;
 
With potassium hydroxide;
 
With triethylamine; In dichloromethane; Cooling with ice;
 

102089-74-7 Upstream products

  • 100-42-5
    100-42-5

    styrene

  • 73210-14-7
    73210-14-7

    N-chloro-N-sodio-tert-butylcarbamate

  • 24424-99-5
    24424-99-5

    di-tert-butyl dicarbonate

  • 124718-93-0
    124718-93-0

    2-azido-2-phenylethanol

102089-74-7 Downstream products

  • 476352-85-9
    476352-85-9

    [2-(isoquinolin-7-yloxy)-1-phenyl-ethyl]-carbamic acid tert-butyl ester

  • 86217-38-1
    86217-38-1

    4-phenyl-2-oxazolidinone

  • 552331-34-7
    552331-34-7

    (2S)-[1-(3,5-dibromo-phenoxymethyl)-2-(1H-indol-3-yl)-ethyl]-carbamic acid tert-butyl ester

  • 552331-46-1
    552331-46-1

    (2-hydroxy-1-phenyl-ethyl)-carbamic acid tert-butyl ester

;

Relevant Products

Contact Now

Submit

Contact us

Address:Room 1-11-1, No. 19 of North Tianshan Road, Deyang, SiChuan, China

Tel:+86-838-2274206/+86-838-2850606

Phone:+86-15328698287

Email:sales@biots.cn

Maps

Home About us Products R&D News Contact

links

Copyright @2009-2025 SICHUAN TONGSHENG AMINOACID CO.LTD ICP NO.:Zhejiang000000